Reversible repositioning of zinc atoms within single crystals of a zinc polycarboxylate with an open-framework structure.
نویسندگان
چکیده
Upon dehydration at 220 degrees C under vacuum, an open-framework zinc tetrahydrofuran-2,3,4,5-tetracarboxylate undergoes reversible single crystal to single crystal conversion by some of the zinc atoms moving to different positions that are 3 A away. The reverse process occurs at room temperature by exposing dehydrated crystals to air.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 126 34 شماره
صفحات -
تاریخ انتشار 2004